Фазовая диаграмма системы Mg-Ni

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Mg-Ni (Magnesium-Nickel) A.A. Nayeb-Hashemi and J.B. Clark The assessed Mg-Ni phase diagram in the composition range 0 to 34 at.% Ni has been taken from [34Hau]; the Ni-rich region of 80 to 100 at.% Ni from [08Vos]; and the MgNi2 liquidus basically from thermodynamic modeling, incorporating some of the data of [08Vos], [34Hau], and [78Bag]. Agreement with the assessed boundaries is quite satisfactory and is also consistent thermodynamically with the experimental data. [80Som] reported the formation of metallic glasses in Mg-Ni alloys in the composition range 8 to 25 at.% Ni. The alloys were rapidly quenched from the liquid state. The composition range of complete glass formation was 10 to 18 at.% Ni. [80Som] also noted that the transformation of the glassy Mg-Ni alloys to a stable crystal structure occurred via a metastable intermediate phase. [08Vos] reported that Ni and MgNi2 are ferromagnetic below 340 and 235 C, respectively. The reported Curie temperature for Ni is in fair agreement with 360 and 358 C given in [35Aro] and [51Boz], but later investigators [60Wol, 75Bus] disputed the ferromagnetic behavior of MgNi2. 08Vos: G. Voss, Z. Anorg. Chem., 57, 61-67 (1908) in German. 34Hau: J.L. Haughton and R.J. Payne, J. Inst. Met., 54, 275-283 (1934). 35Aro: A. Aron, Compt. Rend., 200, 228-230 (1935) in French. 51Boz: R.M. Bozorth, Ferromagnetism, R.M. Bozorth, Ed., D. Van Nostrand, New York, 271 (1951). 60Wol: J.S. Wollam and E.E. Wallace, J. Phys. Chem. Solids, 13, 212-220 (1960). 75Bus: K.H.J. Buschow, Solid State Commun., 17, 891-893 (1975). 78Bag: P. Bagnoud and P. Feschotte, Z. Metallkd., 69, 114-120 (1978) in French. 80Som: F. Sommer, G. Bucher, and B. Predel, J. Phys. Coll. C8, 41(8), 563-566 ( 1980). Published in Phase Diagrams of Binary Nickel Alloys, 1991, Phase Diagrams of Binary Magnesium Alloys, 1988, and Bull. Alloy Phase Diagrams, 6(3), Jun 1985. Complete evaluation contains 1 figure, 8 tables, and 30 references. Special Points of the Mg-Ni System