Фазовая диаграмма системы Se-Sn

К оглавлению: Другие диаграммы (Others phase diargams)

Se-Sn (Selenium-Tin) R.C. Sharma and Y.A. Chang The assessed Sn-Se phase diagram is based primarily on the work of [06Pel], [ 09Pel], [64Vas], [66Kha], [68Gas], [71Mel], and [82Ale]. The liquid miscibility gap in the (Sn)-SnSe region and the Se-rich portion of the liquidus have not been determined experimentally and are thus shown as dashed lines in the assessed diagram. Two eutectics, L1 = (Sn) + SnSe and L2 = SnSe2 + (Se), are very close to pure Sn and pure Se, respectively, and have not been determined experimentally. In the assessed diagram, the eutectic temperatures for these reactions are arbitrarily shown at ~1 C below the melting points of pure Sn and pure Se, respectively. The monotectic, L2 = L1 + SnSe, in the (Sn)-SnSe region and the eutectic, L2 = SnSe + SnSe2, between SnSe and SnSe2 have been determined by [ 66Kha] and [82Ale]. The mutual solid solubilities of Sn and Se are very limited. [38Jen] reported the solubility of Se in (Sn) to be 0.05 at.% Se at 200 C. There are no reported measurements of the solubility of Sn in (Se). 06Pel: H. Pelabon and H. Moissan, Compt. Rend., 142, 1147-1149 (1906) in French. 09Pel: H. Pelabon, Ann. Chim. Phys., 17, 526-566 (1909) in French. 38Jen: E. Jenckel and L. Roth, Z. Metallkd., 30, 135-144 (1938) in German. 64Vas: T.V. Vasilenko and Y.I. Khar'kov, Fiz. Met. Metalloved., 18(2), 203-209 (1964) in Russian; TR: Phys. Met. Metallogr., 18(2), 45-50 (1964). 66Kha: M.I. Kharakhanova, A.S. Pashinkin, and A.V. Novoselova, Izv. Akad. Nauk SSSR, Neorg. Mater., 2, 1186-1189 (1966) in Russian. 68Gas: A.M. Gas'kov, V.P. Zlomanov, Y.A. Sapozhnikov, and A.V. Novoselova, Vest. Mosk. Univ. Khim., 23(3), 48-51 (1968) in Russian; TR: Moscow Univ. Chem. Bull., 23(3), 30-31 (1968). 71Mel: B.T. Melekh, N.B. Stepanova, T.A. Fomina, and S.A. Semenkovich, Zh. Fiz. Khim., 45(8), 2018-2020 (1971) in Russian; TR: Russ. J. Phys. Chem., 45(8), 1144-1145 (1971). 82Ale: E.A. Aleshina, V.P. Zlomanov, and A.V. Novoselova, Izv. Akad. Nauk SSSR, Neorg. Mater., 18(6), 913-916 (1982) in Russian; TR: Inorg. Mater., 18(6), 765-767 (1982). Published in Bull. Alloy Phase Diagrams, 7(1), Feb 1986. Complete evaluation contains 3 figures, 5 tables, and 26 references. Special Points of the Sn-Se System