Фазовая диаграмма системы Te-Tm

К оглавлению: Другие диаграммы (Others phase diargams)


Te-Tm (Tellurium-Thulium) Editor The Te-Tm phase diagram is redrawn from [76Eli]. The region between Te3Tm2 and TeTm is a continuous solid solution. The 16-fold cationic positions, which are vacant in Te3Tm2, are filled randomly during the subsequent addition of Tm up to the composition of TeTm [76Eli]. At low temperatures (<600 C), separation into Te3Tm2 and TeTm is speculated based on similarity to the Eu-Tm system ( two miscibility gap lines are shown in the original paper). [76Eli] could not confirm Te3Tm reported by [65Par]. Te2Tm is a high-pressure, high-temperature phase [70Can].-H.O. 60Bri: L.H. Brixner, J. Inorg. Nucl. Chem., 15, 199-201 (1960). 65Dis: J.P. Dismukes and J.G. White, Inorg. Chem., 4(7), 970-973 (1965). 65Par: M.P. Pardo, O. Gorochov, J. Flahaut, and L. Domange, Compt. Rend., 260( 6), 1666-1669 (1965) in French. 70Can: J.F. Cannon and H.T. Hall, Inorg. Chem., 9(7), 1639-1643 (1970). 76Eli: A.A. Eliseev, K.A. Zinchenko, V.M. Zemlyanukhina, and C.T. Nguen, Zh. Neorg. Khim., 21(10), 2603-2605 (1976) in Russian; TR: Russ. J. Inorg. Chem., 21(10), 1431-1433 (1976). 1