Фазовая диаграмма системы In-Lu

К оглавлению: Другие диаграммы (Others phase diargams)


In-Lu (Indium-Lutetium) H. Okamoto The assessed Lu-In phase diagram is based primarily on thermal, X-ray, and metallographic analyses of [83Yat]. The accuracy of the temperature scale may be no better than с5 C, because all temperatures quoted by [83Yat] are rounded to the nearest 10 C. The solubility of Lu in (In) is less than 0.011 at.% [74Die]. Significantly in disagreement with the assessed diagram, [85Vas] proposed a diagram that included Lu3In (25 to 32 at.% Lu, stable above 350 C), Lu2In (33. 3 to 33.5 at.% In), Lu3In2 (40 to 42 at.% In, melting congruently at the highest temperature for the Lu-In system), LuIn, and Lu2In5 (71.4 at.% In), based on emf and X-ray investigations. Because some of the phases identified by [85Vas] would be unique in the RE-In systems and because they provided no structural or thermal analysis data, the diagram of [85Vas] was not considered in this assessment. However, more detailed studies are needed to confirm or refute the diagram of [85Vas]. 64Kuz: Yu.B. Kuz'ma and V.Ya. Markiv, Kristallografiya., 9(2), 279-280 (1964) in Russian; TR: Sov. Phys. Crystallogr., 9(2), 218-220 (1964). 65Har: I.R. Harris and G.V. Raynor, J. Less-Common Met., 9, 7-19 (1965). 68Pal: A. Palenzona, J. Less-Common Met., 16, 379-384 (1968). 70Hav: E.E. Havinga, H. Damsma, and M.H. Van Maaren, J. Phys. Chem. Solids, 31, 2653-2662 (1970). 74Die: E.N. Dieva, Physicochemical Studies of Liquid Metals and Alloys, V.G. Bamburov, Ed., Izd. Ural'sk. Nauch. Tsentra Akad. Nauk SSSR, Sverdlovsk, 98- 104 (1974). 83Yat: S.P. Yatsenko, A.A. Semyannikov, H.O. Shakarov, and E.G. Fedorova, J. Less-Common Met., 90(1), 95-108 (1983). 85Vas: V.P. Vasil'ev, V.D. Kkhue, and Ya.I. Gerasimov, Zh. Fiz. Khim., 59(11), 2694-2698 (1985) in Russian; TR: Russ. J. Phys. Chem., 59(11), 1613-1615 (1985) . Submitted to the APD Program. Complete evaluation contains 1 figure, 3 tables, and 10 references. Special Points of the Lu-In System